有机合成导论 第七章：含杂原子化合物

Chaper t7Com oupdns ontaCining Htereotoma1 E)the ard animnOeCO

-OBrFGI

OHFIGCO2

RO2RC

HN

HN H

BrB

r H HN r

HB N

N H NHCl H

HOLiAl4HO

NN

NOHLiAHl4

r oNa/EtO(SHo)LliAl4Ho r2/PHdLilH4 or HA2/Pdo rN /EatHOS(l)

oNH2 RCN

RCH2 NH2 RH2

RNNO2

OGFIO

NH

HN

lCH

NH FGIO

HO

NH OHO HNMe

OM eO NH2

GFI

MOeMeO ON2FGI

eO MMe OeO MON Br2C N MeO MO

eCO HC3HN2O

FG

IeO MMOe NMeOFGI

FG

IH2NNO2NO

O2 N2WorkOMe MOe MOeMe O NH2

)eHetocycyrle ONMe

OEt O MeNH

O GFIOE tH3NHC

2OOEt O OtEO

BrO

HO2EC tON O ONCOE2 Ot

OCE2tO O O tE EOtCHO

O2Ct

O OEt

E

OO EtO Et

HNOH2NFG

INN

BO

O

rO

OOO N H NGF

I OO NH ONOO O N HO NO OR NHO R N'R R'

N eMCHON e

O

CMHOO

rB

OCE2

tO

OOO

O

O

NH N

OON H2HN2 OEt

O HN O HNO HN2 tEOO N HHH N OOH

H

NFGIN

CNO

OCH3MgI

O

OHO

OCl

OO OE OtrB

O OOO CHN AllC3

OA lC3 lO OHH

O HO1. OSCl2 2 .lCAl3

O HOCN

O

OHK EOt HHO2

OO O31. MeLi .2H +OOHHNH2H LOAliH

4C

O

NNO

O

HCO4

lWo

rk

O2CeMO2N S OMe OH O S MOeH OO HNH